منابع مشابه
Detailed Comparison of the Pnicogen Bond with Chalcogen, Halogen and Hydrogen Bonds
The characteristics of the pnicogen bond are explored using a variety of quantum chemical techniques. In particular, this interaction is compared with its halogen and chalcogen bond cousins, as well as with the more common H-bond. In general, these bonds are all of comparable strength. More specifically, they are strengthened by the presence of an electronegative substituent on the electron-acc...
متن کاملNovel Noncovalent Interactions in Catalysis: A Focus on Halogen, Chalcogen, and Anion-π Bonding
Noncovalent interactions play an important role in many biological and chemical processes. Among these, hydrogen bonding is very well studied and is already routinely used in organocatalysis. This Short Review focuses on three other types of promising noncovalent interactions. Halogen bonding, chalcogen bonding, and anion-π bonding have been introduced into organocatalysis in the last few years...
متن کاملTheoretical Study of Intramolecular Interactions in Peri-Substituted Naphthalenes: Chalcogen and Hydrogen Bonds.
A theoretical study of the peri interactions, both intramolecular hydrogen (HB) and chalcogen bonds (YB), in 1-hydroxy-8YH-naphthalene, 1,4-dihydroxy-5,8-di-YH-naphthalene, and 1,5-dihydroxy-4,8-di-YH-naphthalene, with Y = O, S, and Se was carried out. The systems with a OH:Y hydrogen bond are the most stable ones followed by those with a chalcogen O:Y interaction, those with a YH:O hydrogen bo...
متن کاملEnergetic Effects of Multiple Hydrogen Bonds. Implications for Enzymatic Catalysis
The rate enhancements obtained by enzymes often require greater than 20 kcaVmol of stabilization that is specific to the transition state. Inspection of active sites suggests that enzymes often use multiple interactions with substrate groups undergoing charge rearrangement to help provide this preferential stabilization. We have analyzed the deprotonation, in DMSO, of benzoic acids with one or ...
متن کاملMetal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen‐Substituted Alkenes and Dienes
This review covers recent achievements in metal-catalyzed Z-H and Z-Z (Z=S, Se) bond addition to the triple bonds of alkynes-a convenient and atom-efficient way to carbon-element bond formation. Various catalytic systems (both homogeneous and heterogeneous) developed to date to obtain mono- and bis-chalcogen-substituted alkenes or dienes, as well as carbonyl compounds or heterocycles, starting ...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2016
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.201611019